Gustav Mahler (1860-1911) wrote his Symphony No. 5 in 1901-1902. This symphony is an often performed piece of the orchestral repertoire. It calls for four flutes; all of them doubling on piccolo (the 1st and 2nd flutes play piccolo for only 2 measures at the end of the Scherzo).
At the end of the 5th movement, Rondo - Finale, 8 measures before number 35, all four flutes play two high trills in rapid succession.